Cetyl alcohol
Encyclopedia
Cetyl alcohol, also known as 1-hexadecanol and palmityl alcohol, is a fatty alcohol
with the chemical formula
CH3(CH2)15OH. At room temperature, cetyl alcohol takes the form of a wax
y white solid or flakes.
The name cetyl derives from the whale
oil from which it was first isolated.
Michel Chevreul
when he heated spermaceti
, a waxy substance obtained from sperm whale
oil, with caustic potash (potassium hydroxide
). Flakes of cetyl alcohol were left behind on cooling.
, cetyl alcohol is no longer primarily produced from whale oil
but instead either as an end-product of the petroleum
industry, or produced from vegetable oils such as palm oil
and coconut oil
.
in shampoo
s, or as an emollient, emulsifier or thickening agent
in the manufacture of skin creams and lotions. It is also employed as a lubricant
for nuts and bolts.
Fatty alcohol
Fatty alcohols are aliphatic alcohols consisting of a chain of 8 to 22 carbon atoms. Fatty alcohols usually have even number of carbon atoms and a single alcohol group attached to the terminal carbon. Some are unsaturated and some are branched...
with the chemical formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....
CH3(CH2)15OH. At room temperature, cetyl alcohol takes the form of a wax
Wax
thumb|right|[[Cetyl palmitate]], a typical wax ester.Wax refers to a class of chemical compounds that are plastic near ambient temperatures. Characteristically, they melt above 45 °C to give a low viscosity liquid. Waxes are insoluble in water but soluble in organic, nonpolar solvents...
y white solid or flakes.
The name cetyl derives from the whale
Whale
Whale is the common name for various marine mammals of the order Cetacea. The term whale sometimes refers to all cetaceans, but more often it excludes dolphins and porpoises, which belong to suborder Odontoceti . This suborder also includes the sperm whale, killer whale, pilot whale, and beluga...
oil from which it was first isolated.
History
Cetyl alcohol was discovered in 1817 by the French chemistChemist
A chemist is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties such as density and acidity. Chemists carefully describe the properties they study in terms of quantities, with detail on the level of molecules and their component atoms...
Michel Chevreul
Michel Eugène Chevreul
Michel Eugène Chevreul was a French chemist whose work with fatty acids led to early applications in the fields of art and science. He is credited with the discovery of margaric acid and designing an early form of soap made from animal fats and salt...
when he heated spermaceti
Spermaceti
Spermaceti is a wax present in the head cavities of the sperm whale . Originally mistaken for the whales' sperm , spermaceti is created in the spermaceti organ inside the whale's head and connected to its nasal passage...
, a waxy substance obtained from sperm whale
Sperm Whale
The sperm whale, Physeter macrocephalus, is a marine mammal species, order Cetacea, a toothed whale having the largest brain of any animal. The name comes from the milky-white waxy substance, spermaceti, found in the animal's head. The sperm whale is the only living member of genus Physeter...
oil, with caustic potash (potassium hydroxide
Potassium hydroxide
Potassium hydroxide is an inorganic compound with the formula KOH, commonly called caustic potash.Along with sodium hydroxide , this colorless solid is a prototypical strong base. It has many industrial and niche applications. Most applications exploit its reactivity toward acids and its corrosive...
). Flakes of cetyl alcohol were left behind on cooling.
Production
With the demise of commercial whalingWhaling
Whaling is the hunting of whales mainly for meat and oil. Its earliest forms date to at least 3000 BC. Various coastal communities have long histories of sustenance whaling and harvesting beached whales...
, cetyl alcohol is no longer primarily produced from whale oil
Whale oil
Whale oil is the oil obtained from the blubber of various species of whales, particularly the three species of right whale and the bowhead whale prior to the modern era, as well as several other species of baleen whale...
but instead either as an end-product of the petroleum
Petroleum
Petroleum or crude oil is a naturally occurring, flammable liquid consisting of a complex mixture of hydrocarbons of various molecular weights and other liquid organic compounds, that are found in geologic formations beneath the Earth's surface. Petroleum is recovered mostly through oil drilling...
industry, or produced from vegetable oils such as palm oil
Palm oil
Palm oil, coconut oil and palm kernel oil are edible plant oils derived from the fruits of palm trees. Palm oil is extracted from the pulp of the fruit of the oil palm Elaeis guineensis; palm kernel oil is derived from the kernel of the oil palm and coconut oil is derived from the kernel of the...
and coconut oil
Coconut oil
Coconut oil is an edible oil extracted from the kernel or meat of matured coconuts harvested from the coconut palm . Throughout the tropical world, it has provided the primary source of fat in the diets of millions of people for generations. It has various applications in food, medicine, and industry...
.
Uses
Cetyl alcohol is used in the cosmetic industry as a opacifierOpacifier
An opacifier is a substance added to a material in order to make the ensuing system opaque. An example of a chemical opacifier is tin dioxide , which is used to opacify ceramic glazes and milk glass; bone ash is also used....
in shampoo
Shampoo
Shampoo is a hair care product used for the removal of oils, dirt, skin particles, dandruff, environmental pollutants and other contaminant particles that gradually build up in hair...
s, or as an emollient, emulsifier or thickening agent
Thickening agent
Thickening agents, or thickeners, is the term applied to substances which increase the viscosity of a solution or liquid/solid mixture without substantially modifying its other properties; although most frequently applied to foods where the target property is taste, the term also is applicable to...
in the manufacture of skin creams and lotions. It is also employed as a lubricant
Lubricant
A lubricant is a substance introduced to reduce friction between moving surfaces. It may also have the function of transporting foreign particles and of distributing heat...
for nuts and bolts.