Boltwoodite
Encyclopedia
Boltwoodite is a hydrated potassium uranyl
Uranyl
The uranyl ion is an oxycation of uranium in the oxidation state +6, with the chemical formula [UO2]2+. It has a linear structure with short U-O bonds, indicative of the presence of multiple bonds between uranium and oxygen. Four or more ligands are bound to the uranyl ion in an equatorial plane...

 silicate mineral with formula HK(UO2)(SiO4)·1.5(H2O). It is formed from the oxidation and alteration of primary uranium
Uranium
Uranium is a silvery-white metallic chemical element in the actinide series of the periodic table, with atomic number 92. It is assigned the chemical symbol U. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons...

 ores. It takes the form of a crust on some sandstone
Sandstone
Sandstone is a sedimentary rock composed mainly of sand-sized minerals or rock grains.Most sandstone is composed of quartz and/or feldspar because these are the most common minerals in the Earth's crust. Like sand, sandstone may be any colour, but the most common colours are tan, brown, yellow,...

s that bear uranium. These crusts tend to be yellowish with a silky or vitreous luster.

Discovery and occurrence

It was first described in 1956 for an occurrence in Pick's Delta Mine, Delta, San Rafael District (San Rafael Swell
San Rafael Swell
The San Rafael Swell is a large geologic feature located in south-central Utah, USA about 30 miles west of Green River, Utah. The San Rafael Swell, approximately by , consists of a giant dome-shaped anticline of sandstone, shale, and limestone that was pushed up during the Paleocene Laramide...

), Emery County, Utah
Emery County, Utah
Emery County is a county located in the U.S. state of Utah. As of 2000 the population was 10,860, and by 2009 had been estimated to decrease to 10,629. It was named for George W. Emery, governor of the Utah Territory in 1875...

, USA. It is named after Bertram Boltwood
Bertram Boltwood
Bertram Borden Boltwood was an American pioneer of radiochemistry.He graduated from Yale University, and taught there 1897-1900...

 (1870–1927) an American pioneer of radiochemistry.

Boltwoodite occurs as secondary silicate alteration crusts surrounding uraninite
Uraninite
Uraninite is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2, but also contains UO3 and oxides of lead, thorium, and rare earth elements...

 and as fracture fillings. It is found in pegmatite
Pegmatite
A pegmatite is a very crystalline, intrusive igneous rock composed of interlocking crystals usually larger than 2.5 cm in size; such rocks are referred to as pegmatitic....

s and sandstone uranium deposits of the Colorado Plateau
Colorado Plateau
The Colorado Plateau, also called the Colorado Plateau Province, is a physiographic region of the Intermontane Plateaus, roughly centered on the Four Corners region of the southwestern United States. The province covers an area of 337,000 km2 within western Colorado, northwestern New Mexico,...

-type. It occurs associated with uraninite, becquerelite, fourmarierite, phosphouranylite, gypsum
Gypsum
Gypsum is a very soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO4·2H2O. It is found in alabaster, a decorative stone used in Ancient Egypt. It is the second softest mineral on the Mohs Hardness Scale...

 and fluorite
Fluorite
Fluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon...

.
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