Antitaenite
Encyclopedia
Antitaenite is a meteoritic
Meteorite
A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...

 metal alloy
Alloy
An alloy is a mixture or metallic solid solution composed of two or more elements. Complete solid solution alloys give single solid phase microstructure, while partial solutions give two or more phases that may or may not be homogeneous in distribution, depending on thermal history...

 mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...

 composed of iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 and nickel
Nickel
Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...

, 20-40% Ni (and traces of other elements
Chemical element
A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. Familiar examples of elements include carbon, oxygen, aluminum, iron, copper, gold, mercury, and lead.As of November 2011, 118 elements...

) that has a face centered cubic crystal structure
Crystal structure
In mineralogy and crystallography, crystal structure is a unique arrangement of atoms or molecules in a crystalline liquid or solid. A crystal structure is composed of a pattern, a set of atoms arranged in a particular way, and a lattice exhibiting long-range order and symmetry...

. Its existence as a new mineral species occurring in both iron meteorites and in chondrites was first recognized in 1995. There are three other known Fe-Ni meterotic minerals: kamacite
Kamacite
Kamacite is a mineral. It is an alloy of iron and nickel, usually in the proportions of 90:10 to 95:5 although impurities such as cobalt or carbon may be present. On the surface of Earth, it occurs naturally only in meteorites. It has a metallic luster, is gray and has no clear cleavage although...

, taenite
Taenite
Taenite is a mineral found naturally on Earth mostly in iron meteorites. It is an alloy of iron and nickel, with nickel proportions of 20% up to 65%.The name is derived from the Greek for "band". Taenite is a major constituent of iron meteorites...

, and tetrataenite. The pair of minerals antitaenite and taenite constitute the first example in nature of two minerals that have the same crystal structure (face centered cubic) and can have the same chemical composition (same proportions of Fe and Ni) - they differ in their electronic structures: taenite is a high magnetic moment alloy whereas antitaenite is a low magnetic moment alloy. This unique difference in electronic structure was first established in 1999 and arises from a high-magnetic-moment to low-magnetic-moment transition occurring in the Fe-Ni bi-metallic alloy series. The same electronic structure transition is believed to be a causal factor in Invar
Invar
Invar, also known generically as FeNi36 , is a nickel steel alloy notable for its uniquely low coefficient of thermal expansion . The name, Invar, comes from the word invariable, referring to its lack of expansion or contraction with temperature changes.It was invented in 1896 by Swiss scientist...

behaviour.
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