Amaranth (dye)
Encyclopedia
Amaranth, FD&C Red No. 2, E123, C.I. Food Red 9, Acid Red 27, Azorubin S, or C.I. 16185, is a dark red to purple azo dye once used as a food dye and to color cosmetics
Cosmetics
Cosmetics are substances used to enhance the appearance or odor of the human body. Cosmetics include skin-care creams, lotions, powders, perfumes, lipsticks, fingernail and toe nail polish, eye and facial makeup, towelettes, permanent waves, colored contact lenses, hair colors, hair sprays and...

, but since 1976 it has been banned in the United States by the Food and Drug Administration (FDA) as it is a suspected carcinogen
Carcinogen
A carcinogen is any substance, radionuclide, or radiation that is an agent directly involved in causing cancer. This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes...

. It usually comes as a trisodium salt. It has the appearance of reddish-brown, dark red to purple water-soluble powder that decomposes at 120 °C without melting. Its water solution has absorption maximum at about 520 nm. Amaranth is an anionic dye. It can be applied to natural and synthetic fiber
Fiber
Fiber is a class of materials that are continuous filaments or are in discrete elongated pieces, similar to lengths of thread.They are very important in the biology of both plants and animals, for holding tissues together....

s, leather
Leather
Leather is a durable and flexible material created via the tanning of putrescible animal rawhide and skin, primarily cattlehide. It can be produced through different manufacturing processes, ranging from cottage industry to heavy industry.-Forms:...

, paper
Paper
Paper is a thin material mainly used for writing upon, printing upon, drawing or for packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....

, and phenol-formaldehyde resins. As a food additive
Food additive
Food additives are substances added to food to preserve flavor or enhance its taste and appearance.Some additives have been used for centuries; for example, preserving food by pickling , salting, as with bacon, preserving sweets or using sulfur dioxide as in some wines...

 it has E number
E number
E numbers are number codes for food additives that have been assessed for use within the European Union . They are commonly found on food labels throughout the European Union. Safety assessment and approval are the responsibility of the European Food Safety Authority...

 E123. Like all azo dyes, Amaranth was, during the middle of the 20th century, made from coal tar
Coal tar
Coal tar is a brown or black liquid of extremely high viscosity, which smells of naphthalene and aromatic hydrocarbons. Coal tar is among the by-products when coal iscarbonized to make coke or gasified to make coal gas...

; modern synthetics are more likely to be made from petroleum byproducts. Amaranth's use is still legal in some countries, notably in the United Kingdom
United Kingdom
The United Kingdom of Great Britain and Northern IrelandIn the United Kingdom and Dependencies, other languages have been officially recognised as legitimate autochthonous languages under the European Charter for Regional or Minority Languages...

 where it is most commonly used to give Glacé cherries their distinctive colour. Its name was taken from Amaranth grain
Amaranth grain
Amaranth has been cultivated as a grain for 8,000 years. The yield of grain amaranth is comparable to rice or maize. It was a staple food of the Aztecs, and was used as an integral part of Aztec religious ceremonies. The cultivation of amaranth was banned by the conquistadores upon their conquest...

, a plant distinguished by its red color and edible protein-rich seeds.

History

After an incident in 1954 involving FD&C Orange Number 1
FD&C Orange Number 1
FD&C Orange Number 1 was one of the first water soluble dyes to be commercialized, and one of seven original food dyes allowed under the Pure Food and Drug Act of June 30, 1906. In the early 1950s, after several cases were reported of sickness in children who had eaten foods with excessive amounts...

, the FDA retested food colors. In 1960 the FDA was given jurisdiction over color additives, limiting the amounts that could be added to foods and requiring producers of food color to ensure safety and proper labeling of colors. Permission to use food additives was given on a provisional basis, which could be withdrawn should safety issues arise. The FDA gave "generally recognized as safe
Generally recognized as safe
Generally recognized as safe is an American Food and Drug Administration designation that a chemical or substance added to food is considered safe by experts, and so is exempted from the usual Federal Food, Drug, and Cosmetic Act food additive tolerance requirements.-History:On January 1, 1958,...

" (GRAS) provisional status to substances already in use, and extended Red No. 2's provisional status 14 times.

In 1971 a Russian study linked the dye to cancer. By 1976 over 1 million pounds of the dye worth $5 million was used as a colorant in $10 billion worth of foods, drugs and cosmetics. Consumer activists
Consumer activism
Consumer activism is activism undertaken on behalf of consumers, to assert consumer rights.-Objectives and tactics:Goals include making goods and services available to consumers safer, better quality, environmentally friendly, and more readily available....

 in the United States
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...

, perturbed by what they perceived as collusion between the FDA and food conglomerates, put pressure on the FDA to ban it. FDA Commissioner Alexander Schmidt defended the dye, as he had earlier defended the FDA against collusion accusations in his 1975 book, stating that the FDA found "no evidence of a public health hazard". Testing by the FDA found no undeniable proof of a health hazard, but did find a statistically significant increase in the incidence of malignant tumors in female rats given a high dosage of the dye, and concluded that since there could also no longer be a presumption of safety, that use of the dye should be discontinued. The FDA banned FD&C Red No. 2 in 1976. FD&C Red No. 40
Allura Red AC
Allura Red AC is a red azo dye that goes by several names including: Allura Red, Food Red 17, C.I. 16035, FD&C Red 40, 2-naphthalenesulfonic acid, 6-hydroxy-5--, disodium salt, and disodium 6-hydroxy-5--2-naphthalenesulfonate. It is used as a food dye and has the E number E129...

(Allura Red AC) replaced the banned Red No. 2.
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