Alkali anion exchange membrane
Encyclopedia
An alkali anion exchange membrane (AAEM) is a semipermeable membrane
Semipermeable membrane
A semipermeable membrane, also termed a selectively permeable membrane, a partially permeable membrane or a differentially permeable membrane, is a membrane that will allow certain molecules or ions to pass through it by diffusion and occasionally specialized "facilitated diffusion".The rate of...

 generally made from ionomer
Ionomer
An ionomer is a polymer that comprises repeat units of both electrically neutral repeating units and a fraction of ionized units...

s and designed to conduct anions while being impermeable to gases such as oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

 or hydrogen
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...

. This is their essential function when incorporated into a membrane electrode assembly
Membrane electrode assembly
A membrane electrode assembly is an assembled stack of proton exchange membranes or alkali anion exchange membrane , catalyst and flat plate electrode used in a fuel cell.-PEM-MEA:...

 (MEA) of a DMFC or DEFC : separation of reactants and transport of anions.

Advantage

The advantage of the alkali
Alkali
In chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. Some authors also define an alkali as a base that dissolves in water. A solution of a soluble base has a pH greater than 7. The adjective alkaline is commonly used in English as a synonym for base,...

 anion exchange membrane in the fuel cell
Fuel cell
A fuel cell is a device that converts the chemical energy from a fuel into electricity through a chemical reaction with oxygen or another oxidizing agent. Hydrogen is the most common fuel, but hydrocarbons such as natural gas and alcohols like methanol are sometimes used...

 is the potential to use non-noble metals such as iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

, cobalt
Cobalt
Cobalt is a chemical element with symbol Co and atomic number 27. It is found naturally only in chemically combined form. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal....

 or nickel
Nickel
Nickel is a chemical element with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile...

 due to the low overpotential
Overpotential
Overpotential is an electrochemical term which refers to the potential difference between a half-reaction's thermodynamically determined reduction potential and the potential at which the redox event is experimentally observed. The term is directly related to a cell's voltage efficiency...

s associated with electrochemical reactions at high pH
PH
In chemistry, pH is a measure of the acidity or basicity of an aqueous solution. Pure water is said to be neutral, with a pH close to 7.0 at . Solutions with a pH less than 7 are said to be acidic and solutions with a pH greater than 7 are basic or alkaline...

. In comparison against Alkaline fuel cell
Alkaline fuel cell
The alkaline fuel cell , also known as the Bacon fuel cell after its British inventor, is one of the most developed fuel cell technologies. NASA has used alkaline fuel cells since the mid-1960s, in Apollo-series missions and on the Space Shuttle. AFCs consume hydrogen and pure oxygen producing...

, alkali anion exchange membrane fuel cells also protect the electrode from solid carbonate
Carbonate
In chemistry, a carbonate is a salt of carbonic acid, characterized by the presence of the carbonate ion, . The name may also mean an ester of carbonic acid, an organic compound containing the carbonate group C2....

 precipitation, which can cause fuel (oxygen/hydrogen) transport problem during start-up.

See also

  • Alkaline fuel cell
    Alkaline fuel cell
    The alkaline fuel cell , also known as the Bacon fuel cell after its British inventor, is one of the most developed fuel cell technologies. NASA has used alkaline fuel cells since the mid-1960s, in Apollo-series missions and on the Space Shuttle. AFCs consume hydrogen and pure oxygen producing...

  • Artificial membrane
    Artificial membrane
    An artificial membrane, or synthetic membrane, is a synthetically created membrane which is usually intended for separation purposes in laboratory or in industry. Synthetic membranes have been successfully used for small and large-scale industrial processes since the middle of twentieth century. A...

  • Gas diffusion electrode
    Gas diffusion electrode
    Gas diffusion electrodes are electrodes with a conjunction of a solid, liquid and gaseous interface, and an electrical conducting catalyst supporting an electrochemical reaction between the liquid and the gaseous phase...

  • Ion exchange
    Ion exchange
    Ion exchange is an exchange of ions between two electrolytes or between an electrolyte solution and a complex. In most cases the term is used to denote the processes of purification, separation, and decontamination of aqueous and other ion-containing solutions with solid polymeric or mineralic 'ion...

  • Glossary of fuel cell terms
    Glossary of fuel cell terms
    The Glossary of fuel cell terms lists the definitions of many terms used within the fuel cell industry. The terms in this fuel cell glossary may be used by fuel cell industry associations, in education material and fuel cell codes and standards to name but a few. –...

  • Proton exchange membrane
    Proton exchange membrane
    A proton exchange membrane or polymer electrolyte membrane is a semipermeable membrane generally made from ionomers and designed to conduct protons while being impermeable to gases such as oxygen or hydrogen...

The source of this article is wikipedia, the free encyclopedia.  The text of this article is licensed under the GFDL.
 
x
OK