Tin(IV) sulfide
Encyclopedia
Tin sulfide is a chemical compound
with the formula
Sn
S2
. The compound crystallizes in the cadmium iodide
motif, with the Sn(IV) situated in "octahedral holes' defined by six sulfide centers. It occurs naturally as the rare mineral
berndtite.
The compound precipitates as a brown solid upon the addition of H2S to solutions of tin(IV) species. This reaction is reversed at low pH. Crystalline SnS2 has a bronze colour and is used in decorative coating where it is known as mosaic gold
.
The material also reacts with sulfide salts to give a series of thiostannates with the formula [SnS2]m[S]n2n− . A simplified equation for this depolymerization reaction is
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...
with the formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....
Sn
Tin
Tin is a chemical element with the symbol Sn and atomic number 50. It is a main group metal in group 14 of the periodic table. Tin shows chemical similarity to both neighboring group 14 elements, germanium and lead and has two possible oxidation states, +2 and the slightly more stable +4...
S2
Sulfur
Sulfur or sulphur is the chemical element with atomic number 16. In the periodic table it is represented by the symbol S. It is an abundant, multivalent non-metal. Under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S8. Elemental sulfur is a bright yellow...
. The compound crystallizes in the cadmium iodide
Cadmium iodide
Cadmium iodide, CdI2, is a chemical compound of cadmium and iodine. It is notable for its crystal structure, which is typical for compounds of the form MX2 with strong polarization effects.-Uses:...
motif, with the Sn(IV) situated in "octahedral holes' defined by six sulfide centers. It occurs naturally as the rare mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...
berndtite.
The compound precipitates as a brown solid upon the addition of H2S to solutions of tin(IV) species. This reaction is reversed at low pH. Crystalline SnS2 has a bronze colour and is used in decorative coating where it is known as mosaic gold
Mosaic gold
Mosaic gold, or stannic sulfide, SnS2, is obtained as a yellow scaly crystalline powder, and used as a pigment in bronzing and gilding wood and metal work. It was called by the alchemists aurum musivum, or aurum mosaicum...
.
The material also reacts with sulfide salts to give a series of thiostannates with the formula [SnS2]m[S]n2n
- SnS2 + S2
− → 1/x{SnS32− }x.