Protectionist Party
| Portfolio | Minister |
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| Prime Minister and Minister for External Affairs | Hon Alfred Deakin Alfred Deakin Alfred Deakin , Australian politician, was a leader of the movement for Australian federation and later the second Prime Minister of Australia. In the last quarter of the 19th century, Deakin was a major contributor to the establishment of liberal reforms in the colony of Victoria, including the... , MP |
| Treasurer | Rt Hon Sir John Forrest John Forrest Sir John Forrest GCMG was an Australian explorer, the first Premier of Western Australia and a cabinet minister in Australia's first federal parliament.... , GCMG MP |
| Attorney-General | Hon Isaac Isaacs Isaac Isaacs Sir Isaac Alfred Isaacs GCB GCMG KC was an Australian judge and politician, was the third Chief Justice of Australia, ninth Governor-General of Australia and the first born in Australia to occupy that post. He is the only person ever to have held both positions of Chief Justice of Australia and... , KC MP (to 12 October 1906)
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| Minister for Home Affairs | Hon Littleton Groom Littleton Groom Sir Littleton Ernest Groom, KCMG was an Australian Commonwealth Minister, Speaker of the House of Representatives and Australia's 17th longest serving federal Parliamentarian . He was a member of every non-Australian Labor Party ministry from 1905 to 1926... , MP (to 12 October 1906)
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| Minister for Trade and Customs | Hon Sir William Lyne William Lyne Sir William John Lyne KCMG , Australian politician, was Premier of New South Wales and a member of the first federal ministry.-Early life:... , KCMG MP |
| Minister for Defence | Senator Hon Thomas Playford Thomas Playford II Thomas Playford served as Premier of South Australia from 11 June 1887 to 26 June 1889 and 8 August 1890 to 20 June 1892, as well as serving as the Australian Federal Minister for Defence from 1905 to 1907.... |
| Postmaster-General | Hon Austin Chapman Austin Chapman Sir Austin Chapman KCMG , Australian politician, was a member of several early federal ministries. He was born in Bong Bong near Bowral, New South Wales and educated at Marulan Public School and was apprenticed as a saddler at an early age... , MP |
| Vice-President of the Executive Council | Hon Thomas Ewing Thomas Ewing (Australian politician) Sir Thomas Thomson Ewing KCMG was an Australian politician.-Early life:Ewing was born at Pitt Town, New South Wales to clergyman Thomas Campbell Ewing and Elizabeth, née Thomson. Despite an intention to study for the Bar, he joined a surveyor's party at the age of 17, and became a licensed... (to 12 October 1906)
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| Ministers without portfolios | Senator Hon John Keating John Keating (Australian politician) John Henry Keating was an Australian politician.Keating was born in Hobart and educated at Officer College, Hobart, Saint Ignatius' College, Riverview, Sydney and the University of Tasmania where he received a Bachelor of Laws in 1896... (to 12 October 1906)
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