Polymeric membranes
Encyclopedia
Polymeric membranes are membranes
Artificial membrane
An artificial membrane, or synthetic membrane, is a synthetically created membrane which is usually intended for separation purposes in laboratory or in industry. Synthetic membranes have been successfully used for small and large-scale industrial processes since the middle of twentieth century. A...

 that take the form of polymer
Polymer
A polymer is a large molecule composed of repeating structural units. These subunits are typically connected by covalent chemical bonds...

ic interphases, which can selectively transfer certain chemical species
Chemical species
Chemical species are atoms, molecules, molecular fragments, ions, etc., being subjected to a chemical process or to a measurement. Generally, a chemical species can be defined as an ensemble of chemically identical molecular entities that can explore the same set of molecular energy levels on a...

 over others. There are several mechanisms that could be deployed in their functioning. Knudsen diffusion
Knudsen diffusion
Knudsen diffusion is a means of diffusion that occurs in a long pore with a narrow diameter because molecules frequently collide with the pore wall.Consider the diffusion of gas molecules through very small capillary pores...

 and solution diffusion are prominent mechanisms. Polymeric membranes are of particular importance in gas separation
Gas separation
Gas mixtures can be effectively separated by synthetic membranes. For other methods see adsorption, absorption, cryogenic distillation.Membranes are employed in:* separation of nitrogen or oxygen out of air...

 applications. The membrane has high strength. Key industrial applications include: oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

-nitrogen
Nitrogen
Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere...

 separation, removal of organics
Organic compound
An organic compound is any member of a large class of gaseous, liquid, or solid chemical compounds whose molecules contain carbon. For historical reasons discussed below, a few types of carbon-containing compounds such as carbides, carbonates, simple oxides of carbon, and cyanides, as well as the...

 and natural gas
Natural gas
Natural gas is a naturally occurring gas mixture consisting primarily of methane, typically with 0–20% higher hydrocarbons . It is found associated with other hydrocarbon fuel, in coal beds, as methane clathrates, and is an important fuel source and a major feedstock for fertilizers.Most natural...

enrichment.

Advances in polymeric membranes

  • The University of Minnesota developed a nanostructure membrane that has a narrow pore size which allows for tunable selectivity of solutes. The membrane is also extremely strong compared to other membranes.
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