Paper battery
Encyclopedia
A paper battery is a battery
Battery (electricity)
An electrical battery is one or more electrochemical cells that convert stored chemical energy into electrical energy. Since the invention of the first battery in 1800 by Alessandro Volta and especially since the technically improved Daniell cell in 1836, batteries have become a common power...

 engineered to use a spacer formed largely of cellulose
Cellulose
Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to over ten thousand β linked D-glucose units....

 (the major constituent of paper).

This technology can also be used in supercapacitors.
It incorporates nanoscale
Nanoscopic scale
The nanoscopic scale usually refers to structures with a length scale applicable to nanotechnology, usually cited as 1-100 nanometers. The nanoscopic scale is a lower bound to the mesoscopic scale for most solids....

 structures to act as high surface-area electrodes to improve the conduction of electricity.

Development

The creation of this unique nanocomposite paper drew from a diverse pool of disciplines, requiring expertise in materials science, energy storage, and chemistry. In August 2007, a research team at Rensselaer Polytechnic Institute
Rensselaer Polytechnic Institute
Stephen Van Rensselaer established the Rensselaer School on November 5, 1824 with a letter to the Rev. Dr. Samuel Blatchford, in which van Rensselaer asked Blatchford to serve as the first president. Within the letter he set down several orders of business. He appointed Amos Eaton as the school's...

 (led by Drs. Robert Linhardt, the Ann and John H. Broadbent Senior Constellation Professor of Biocatalysis and Metabolic Engineering at Rensselaer; Pulickel M. Ajayan, professor of materials science and engineering; and Omkaram Nalamasu, professor of chemistry with a joint appointment in materials science and engineering) developed the paper battery.
Senior research specialist Victor Pushparaj, along with postdoctoral research associates Shaijumon M. Manikoth, Ashavani Kumar, and Saravanababu Murugesan, were co-authors and lead researchers of the project. Other co-authors include research associate Lijie Ci and Rensselaer Nanotechnology Center Laboratory Manager Robert Vajtai.

This cellulose based spacer is compatible with many possible electrolytes. Researchers used ionic liquid
Ionic liquid
An ionic liquid is a salt in the liquid state. In some contexts, the term has been restricted to salts whose melting point is below some arbitrary temperature, such as . While ordinary liquids such as water and gasoline are predominantly made of electrically neutral molecules, ILs are largely made...

, essentially a liquid salt, as the battery’s electrolyte
Electrolyte
In chemistry, an electrolyte is any substance containing free ions that make the substance electrically conductive. The most typical electrolyte is an ionic solution, but molten electrolytes and solid electrolytes are also possible....

, as well as naturally occurring electrolytes such as human sweat, blood, and urine.

Ionic liquid, which contains no water, would mean that there’s nothing in the batteries to freeze or evaporate, potentially allowing operation in extreme temperatures.

Naturally occurring electrolytes might allow more biocompatible batteries.
According to Pushparaj “It’s a way to power a small device such as a pacemaker without introducing any harsh chemicals – such as the kind that are typically found in batteries — into the body.”

Durability

The spacer is an integrated combination of spacer, and electrodes. “It’s essentially a regular piece of paper, but it’s made in a very intelligent way,” said Linhardt, “We’re not putting pieces together — it’s a single, integrated device,” he said. “The components are molecularly attached to each other: the carbon nanotube print is embedded in the paper, and the electrolyte is soaked into the paper. The end result is a device that looks, feels, and weighs the same as paper.”

Uses

The paper-like quality of the battery combined with the structure of the nanotubes embedded within gives them their light weight and low cost, making them attractive for portable electronics, aircraft
Aircraft
An aircraft is a vehicle that is able to fly by gaining support from the air, or, in general, the atmosphere of a planet. An aircraft counters the force of gravity by using either static lift or by using the dynamic lift of an airfoil, or in a few cases the downward thrust from jet engines.Although...

, automobile
Automobile
An automobile, autocar, motor car or car is a wheeled motor vehicle used for transporting passengers, which also carries its own engine or motor...

s, and toys (such as model aircraft
Model aircraft
Model aircraft are flying or non-flying models of existing or imaginary aircraft using a variety of materials including plastic, diecast metal, polystyrene, balsa wood, foam and fibreglass...

), while their ability to use electrolytes in blood make them potentially useful for medical devices such as pacemakers. The medical uses are particularly attractive because they do not contain any toxic materials and can be biodegradable; a major drawback of chemical cells. However, Professor Sperling cautions that commercial applications may be a long way away, because nanotubes are still relatively expensive to fabricate. Currently they are making devices a few inches in size. In order to be commercially viable, they would like to be able to make them newspaper size; a size which, taken all together, would be powerful enough to power a car.
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