Pallaviciniites
Encyclopedia
The lowermost Upper Devonian fossil Pallaviciniites was for a time the oldest known liverwort until Metzgeriothallus
Metzgeriothallus
Metzgeriothallus sharona is the oldest known liverwort fossil, dating to the Middle Devonian. It is a simple, thalloid organism. M. metzgerioides is known from more fragmentary material dating to the Carboniferous of Scotland....

was recovered from earlier Devonian strata.

It had a central axis, and bifurcated at its tips; similar fossils have been found in younger strata through to the Pleistocene. With the exception of its elongated axial conducting (non-vascular) cells, the thallus was a single cell thick. It had a serrated margin.

Prior to its discovery, the oldest known liverworts dated to the Lower Carboniferous.
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