Niobium(IV) fluoride
Encyclopedia
Niobium fluoride is a chemical compound with the formula
Formula
In mathematics, a formula is an entity constructed using the symbols and formation rules of a given logical language....

 NbF4; it is a nonvolatile black solid
Solid
Solid is one of the three classical states of matter . It is characterized by structural rigidity and resistance to changes of shape or volume. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire volume available to it like a...

. It absorbs vapor strongly. It turns into NbO2F in moist air. NbF4 reacts with water strongly to form brown solution and brown precipitate whose components are unknown. It is stable between 275℃ and 325℃ when heating NbF4 in vacuum. However, it takes disproportionating reaction over 350℃ rapidly to form niobium(V) fluoride
Niobium(V) fluoride
Niobium fluoride, also known as niobium pentafluoride, is a colorless crystalline solid often used as a starting material in niobium chemistry.-Preparation:...

 and niobium(III) fluoride:
(at 350℃)
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