
Luttinger parameter
Encyclopedia
In semiconductors, valence bands are well characterized by 3 Luttinger parameters. At the Г-point in the band structure,
and
orbitals form valence bands. But spin-orbit coupling splits sixfold degeneracy into high energy 4-fold and lower energy 2-fold bands. Again 4-fold degeneracy is lifted into heavy- and light hole bands by phenomenological Hamiltonian by J. M. Luttinger.
, total angular momentum should take part in. From the three valence band, l=1 and s=1/2 state generate six state of |j,mj> as
The spin-orbit interaction from the relativistic quantum mechanics, lowers the energy of j=1/2 states down.

Phenomenological Luttinger parameters
are defined as

and

If we take
as
, the Hamiltonian is diagonalized for j=3/2 states.

Two degeneated resulting eigenenergies are
for 
for 
(
) indicates heav-(light-) hole band energy. If we regard the electrons as nearly free electrons, the Luttinger parameters describe effective mass
of electron in each bands.



Three valence band state
In the presence of spin-orbit interactionSpin-orbit interaction
In quantum physics, the spin-orbit interaction is any interaction of a particle's spin with its motion. The first and best known example of this is that spin-orbit interaction causes shifts in an electron's atomic energy levels due to electromagnetic interaction between the electron's spin and...
, total angular momentum should take part in. From the three valence band, l=1 and s=1/2 state generate six state of |j,mj> as

The spin-orbit interaction from the relativistic quantum mechanics, lowers the energy of j=1/2 states down.
Phenomenological Hamiltonian for the j=3/2 states
Phenomenological Hamiltonian in spherical approximation is written as
Phenomenological Luttinger parameters


and

If we take



Two degeneated resulting eigenenergies are






Effective mass
In solid state physics, a particle's effective mass is the mass it seems to carry in the semiclassical model of transport in a crystal. It can be shown that electrons and holes in a crystal respond to electric and magnetic fields almost as if they were particles with a mass dependence in their...
of electron in each bands.
Measurement of Luttinger parameters
Luttinger parameter can be measured by Hot-electron luminescence experiment.Example: GaAs
