Lumisterol
Encyclopedia
Lumisterol is a compound that is part of the vitamin D
Vitamin D
Vitamin D is a group of fat-soluble secosteroids. In humans, vitamin D is unique both because it functions as a prohormone and because the body can synthesize it when sun exposure is adequate ....

 family of steroid
Steroid
A steroid is a type of organic compound that contains a characteristic arrangement of four cycloalkane rings that are joined to each other. Examples of steroids include the dietary fat cholesterol, the sex hormones estradiol and testosterone, and the anti-inflammatory drug dexamethasone.The core...

 compounds. It is the (9β,10α) stereoisomer of ergosterol
Ergosterol
Ergosterol is a sterol found in fungi, and named for ergot, a common name for the members of the fungal genus Claviceps from which ergosterol was first isolated. Ergosterol does not occur in plant or animal cells...

 and was produced as a photochemical by-product in the preparation of vitamin D1, which was a mixture of vitamin D2
Ergocalciferol
Ergocalciferol is a form of vitamin D, also called vitamin D2. It is marketed under various names including Deltalin , Drisdol and Calcidol...

 and lumisterol. Vitamin D2 can be formed from lumisterol by a electrocyclic ring opening and subsequent sigmatropic [1,7] hydride shift.
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