Holmium(III) chloride
Encyclopedia
Holmium chloride is the inorganic compound
Inorganic compound
Inorganic compounds have traditionally been considered to be of inanimate, non-biological origin. In contrast, organic compounds have an explicit biological origin. However, over the past century, the classification of inorganic vs organic compounds has become less important to scientists,...

 with the formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 Ho
Holmium
Holmium is a chemical element with the symbol Ho and atomic number 67. Part of the lanthanide series, holmium is a rare earth element. Its oxide was first isolated from rare earth ores in 1878 and the element was named after the city of Stockholm....

Cl3
Chloride
The chloride ion is formed when the element chlorine, a halogen, picks up one electron to form an anion Cl−. The salts of hydrochloric acid HCl contain chloride ions and can also be called chlorides. The chloride ion, and its salts such as sodium chloride, are very soluble in water...

. It is a common salt but is mainly used in research. It exhibits the same color-changing behavior seen in holmium oxide, being a yellow in natural lighting and a bright pink color in fluorescent lighting.

Preparation

It forms upon union of the elements, but a more commonly used method involves heating a mixture of holmium(III) oxide
Holmium(III) oxide
Holmium oxide, or holmium oxide is a chemical compound of a rare-earth element holmium and oxygen with the formula Ho2O3. Together with dysprosium oxide holmium oxide is one of the most powerfully paramagnetic substances known. The oxide, also called holmia, occurs as a component of the related...

 and ammonium chloride
Ammonium chloride
Ammonium chloride NH4Cl is an inorganic compound with the formula NH4Cl. It is a white crystalline salt that is highly soluble in water. Solutions of ammonium chloride are mildly acidic. Sal ammoniac is a name of natural, mineralogical form of ammonium chloride...

 at 200-250 °C:
Ho2O3 + 6 NH4Cl → 2 HoCl3 + 6 NH3 + 2 H2O

Structure

In the solid state it has the YCl3
Yttrium(III) chloride
Yttrium chloride is an ionic compound of yttrium and chlorine. It is a salt that is solid at room temperature, highly soluble in water, and deliquescent...

layer structure.
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