Catalytic bead sensor
Encyclopedia
A catalytic bead sensor is a type of sensor
Sensor
A sensor is a device that measures a physical quantity and converts it into a signal which can be read by an observer or by an instrument. For example, a mercury-in-glass thermometer converts the measured temperature into expansion and contraction of a liquid which can be read on a calibrated...

 that is used for gas detection
Gas detector
A gas detector is a device which detects the presence of various gases within an area, usually as part of a safety system. This type of equipment is used to detect a gas leak and interface with a control system so a process can be automatically shut down...

.

Principle

The catalytic bead sensor consist of two coils of fine platinum wire each embedded in a bead of alumina, connected electrically in a Wheatstone bridge
Wheatstone bridge
A Wheatstone bridge is an electrical circuit used to measure an unknown electrical resistance by balancing two legs of a bridge circuit, one leg of which includes the unknown component. Its operation is similar to the original potentiometer. It was invented by Samuel Hunter Christie in 1833 and...

 circuit. One of the pellistor
Pellistor
A pellistor is a solid-state device used to detect gases which are either combustible or which have a significant difference in thermal conductivity to that of air...

s is impregnated with a special catalyst which promotes oxidation whilst the other is treated to inhibit oxidation. Current is passed through the coils so that they reach a temperature at which oxidation of a gas readily occurs at the catalysed bead (500-550°C). Passing combustible gas raises the temperature further which increases the resistance of the platinum coil in the catalysed bead, leading to an imbalance of the bridge. This output change is linear, for most gases, up to and beyond 100% LEL, response time is a few seconds to detect alarm levels (around 20% LEL), at least 12% oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

 by volume is needed for the oxidation.

Issues

  • Catalyst poisoning
    Catalyst poisoning
    Catalyst poisoning refers to the effect that a catalyst can be 'poisoned' if it reacts with another compound that bonds chemically to its active surface sites. This effectively reduces the usefulness of the catalyst...

     - because of the direct contact of the gas with the catalytic surface it may be deactivated in some circumstances.
  • Sensor drift - Decreased sensitivity may occur depending on operating and ambient conditions.
  • Modes of failure - which include poisoning and sinter blockage, they become apparent during routine maintenance checking.
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