Barium ferrite
Encyclopedia
Barium ferrite, abbreviated BaFe, is the chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

 with the formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 BaFe2O4. This and related ferrite
Ferrite (iron)
Ferrite or alpha iron is a materials science term for iron, or a solid solution with iron as the main constituent, with a body centred cubic crystal structure. It is the component which gives steel and cast iron their magnetic properties, and is the classic example of a ferromagnetic material...

 materials are components in magnetic stripe card
Magnetic stripe card
A magnetic stripe card is a type of card capable of storing data by modifying the magnetism of tiny iron-based magnetic particles on a band of magnetic material on the card...

s. BaFe is described as Ba2+(Fe3+)2(O2-)4. The Fe3+ centers, with a high-spin
Crystal field theory
Crystal field theory is a model that describes the electronic structure of transition metal compounds, all of which can be considered coordination complexes. CFT successfully accounts for some magnetic properties, colours, hydration enthalpies, and spinel structures of transition metal complexes,...

 d5 configuration, are ferromagnetic
Ferromagnetism
Ferromagnetism is the basic mechanism by which certain materials form permanent magnets, or are attracted to magnets. In physics, several different types of magnetism are distinguished...

ally coupled. This area of technology is usually considered to be an application of the related fields of materials science
Materials science
Materials science is an interdisciplinary field applying the properties of matter to various areas of science and engineering. This scientific field investigates the relationship between the structure of materials at atomic or molecular scales and their macroscopic properties. It incorporates...

 and solid state chemistry. It is also used in subwoofer
Subwoofer
A subwoofer is a woofer, or a complete loudspeaker, which is dedicated to the reproduction of low-pitched audio frequencies known as the "bass". The typical frequency range for a subwoofer is about 20–200 Hz for consumer products, below 100 Hz for professional live sound, and below...

 magnets to provide power.

A related family of industrially useful "hexagonal ferrites" are known, also containing barium. In contrast to the usual spinel structure, these materials feature hexagonally close-packed framework of oxides. Furthermore some the oxygen centers are replaced by Ba2+ ions. Formulas for these species include BaFe12O19, BaFe15O23, and BaFe18O27. Thus, BaFe12O19 is related to Fe12O20, with the empirical formula Fe3O4, i.e. magnetite
Magnetite
Magnetite is a ferrimagnetic mineral with chemical formula Fe3O4, one of several iron oxides and a member of the spinel group. The chemical IUPAC name is iron oxide and the common chemical name is ferrous-ferric oxide. The formula for magnetite may also be written as FeO·Fe2O3, which is one part...

.

Barium ferrites are robust ceramic
Ceramic
A ceramic is an inorganic, nonmetallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...

s that are generally stable to moisture and corrosion-resistant.
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