Arsenate mineral
Encyclopedia
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3- anion group and, more rarely, other arsenates with anions like AsO3(OH)2- (also written HAsO42-) (example: pharmacolite Ca(AsO3OH).2H2O) or (very rarely) [AsO2(OH)2]- (example: andyrobertsite
). Arsenite minerals
are much less common. Both the Dana and the Strunz
mineral classifications place the arsenates in with the phosphate minerals
.
Example arsenate minerals include:
-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz
(10 ed, pending publication).
Andyrobertsite
Andyrobertsite is a rare, complex arsenate mineral with a blue color. It is found in the Tsumeb mine in Namibia and named after Andrew C. Roberts , mineralogist with the Geological Survey of Canada. A Ca-rich analogue is called calcioandyrobertsite and has a more greenish tint....
). Arsenite minerals
Arsenite minerals
Arsenite minerals are very rare oxygen-bearing arsenic minerals. Classical world localities where such minerals occur include the complex skarn manganese deposit at Långban and the polymetallic Tsumeb deposit . The most often reported arsenite anion in minerals is the AsO33- anion, present for...
are much less common. Both the Dana and the Strunz
Strunz classification
Nickel–Strunz classification is a scheme for categorizing minerals based upon their chemical composition, introduced by German mineralogist Karl Hugo Strunz in his 1941 Mineralogische Tabellen. The 4th edition was edited by Christel Tennyson too . It was followed by A.S...
mineral classifications place the arsenates in with the phosphate minerals
Phosphate minerals
Phosphate minerals are those minerals that contain the tetrahedrally coordinated phosphate anion along with the freely substituting arsenate and vanadate...
.
Example arsenate minerals include:
- AnnabergiteAnnabergiteAnnabergite is an arsenate mineral consisting of a hydrous nickelarsenate, Ni32·8H2O, crystallizing in the monoclinic system and isomorphous with vivianite and erythrite. Crystals are minute and capillary and rarely met with, the mineral occurring usually as soft earthy masses and encrustations. A...
Ni3(AsO4)2·8H2O - AustiniteAustiniteAustinite is a member of the adelite-descloizite group, adelite subgroup, the Zn end member of the Cu-Zn series with conichalcite. It is the zinc analogue of cobaltaustinite and nickelaustinite. At one time “brickerite” was thought to be a different species, but it is now considered to be identical...
CaZn(AsO4)(OH) - ClinoclaseClinoclaseClinoclase is a hydrous copper arsenate mineral, Cu3AsO43. Clinoclase is a rare secondary copper mineral and forms acicular crystals in the fractured weathered zone above copper sulfide deposits. It occurs in vitreous, translucent dark blue to dark greenish blue colored crystals and botryoidal...
Cu3(AsO4)(OH)3 - ConichalciteConichalciteConichalcite, CaCu, is a relatively common arsenate mineral related to duftite . It is green, often botryoidal, and occurs in the oxidation zone of some metal deposits. It occurs with limonite, malachite, beudantite, adamite, cuproadamite, olivenite and smithsonite.- Formation :Conichalcite forms...
CaCu(AsO4)(OH) - CornubiteCornubiteCornubite is a rare secondary copper arsenate mineral with formula: Cu524. It was first described for its discovery in 1958 in Wheal Carpenter, Gwinear, Cornwall, England, UK. The name is from Cornubia, the medieval Latin name for Cornwall...
Cu5(AsO4)2(OH)4 - Cornwallite Cu2+5(AsO4)2(OH)2
- Erythrite Co3(AsO4)2·8H2O
- MimetiteMimetiteMimetite, whose name derives from the Greek Μιμητής mimethes, meaning "imitator", is an arsenate mineral which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name is a reference to mimetite's resemblance to the mineral pyromorphite...
Pb6(AsO4)3Cl - OliveniteOliveniteOlivenite is a copper arsenate mineral, formula Cu2AsO4OH. It crystallizes in the monoclinic system , and is sometimes found in small brilliant crystals of simple prismatic habit terminated by domal faces...
Cu2(AsO4)OH
Nickel–Strunz Classification -08- Phosphates
IMAInternational Mineralogical Association
The International Mineralogical Association is an international group of 38 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 4000 plus known mineral species...
-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz
Strunz classification
Nickel–Strunz classification is a scheme for categorizing minerals based upon their chemical composition, introduced by German mineralogist Karl Hugo Strunz in his 1941 Mineralogische Tabellen. The 4th edition was edited by Christel Tennyson too . It was followed by A.S...
(10 ed, pending publication).
- Abbreviations:
- "*" - discredited (IMA/CNMNC status).
- "?" - questionable/doubtful (IMA/CNMNC status).
- "REE" - Rare-earth elementRare earth elementAs defined by IUPAC, rare earth elements or rare earth metals are a set of seventeen chemical elements in the periodic table, specifically the fifteen lanthanides plus scandium and yttrium...
(Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) - "PGE" - Platinum-group elementPlatinum groupThe platinum group metals is a term used sometimes to collectively refer to six metallic elements clustered together in the periodic table.These elements are all transition metals, lying in the d-block .The six...
(Ru, Rh, Pd, Os, Ir, Pt) - 03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V[5,6] Vanadates), 09 Silicates:
- Neso: insular (from GreekGreek languageGreek is an independent branch of the Indo-European family of languages. Native to the southern Balkans, it has the longest documented history of any Indo-European language, spanning 34 centuries of written records. Its writing system has been the Greek alphabet for the majority of its history;...
νησος nēsos, island) - Soro: grouping (from Greek σωροῦ sōros, heap, mound (especially of corn))
- Cyclo: ring
- Ino: chain (from Greek ις [genitive: ινος inos], fibre)
- Phyllo: sheet (from Greek φύλλον phyllon, leaf)
- Tekto: three-dimensional framework
- Neso: insular (from Greek
- Nickel–Strunz code scheme: NN.XY.##x
- NN: Nickel–Strunz mineral class number
- X: Nickel–Strunz mineral division letter
- Y: Nickel–Strunz mineral family letter
## x: Nickel–Strunz mineral/group number, x add-on letter
Class: arsenates
- 08.A Arsenates without additional anions, without H2O
- 08.AA With small cations (some also with larger ones): 05 AlarsiteAlarsiteAlarsite is a mineral found in the far Eastern area of Russia. Its name is derived from its composition of Aluminium and Arsenic. Alarsite's Mohs hardness is 5-5½ and has a Trigonal crystal system.- External links :* from mindat.org* from...
- 08.AB With medium-sized cations: 25 XanthiositeXanthiositeXanthiosite is an arsenate mineral first discovered in Germany in 1858; it may also be found in Greece. It is not radioactive....
, 30 Lammerite, 35 Stranskiite - 08.AC With medium-sized and large cations: 10 Arseniopleite, 10 Caryinite, 10 Yazganite, 10 Johillerite, 10 Odanielite, 10 Nickenichite, 10 Bradaczekite; 25 Berzeliite, 25 Manganberzeliite, 85 Filatovite
- 08.AD With only large cations: 10 Svenekite, 10 WeiliteWeiliteWeilite is a rare arsenate mineral. It is a translucent white triclinic mineral with a waxy luster.It was first described in 1963 for occurrences in Gabe Gottes Mine, Haut-Rhin, Alsace, France; Wittichen, Schenkenzell, Black Forest, Baden-Württemberg, Germany; and the Schneeberg District,...
; 30 Schultenite, 35 Chernovite-(Y); 50 Gasparite-(Ce), 50 Rooseveltite; 55 Tetrarooseveltite, 60 Chursinite
- 08.AA With small cations (some also with larger ones): 05 Alarsite
- 08.B Arsenates with Additional Anions, without H2O
- 08.BA With small and medium-sized cations: 10 Bergslagite
- 08.BB With only medium-sized cations, (OH, etc.):RO4 £ 1:1: 15 Sarkinite; 30 Zincolivenite, 30 EveiteEveiteEveite is a manganese arsenate mineral in the olivenite group. Its chemical formula is Mn2AsO4OH. It is found only in Långban, Filipstad, Värmland, Sweden and at the Sterling Mine in New Jersey, United States of America. It is a dimorph of sarkinite and is isostructural with adamite...
, 30 OliveniteOliveniteOlivenite is a copper arsenate mineral, formula Cu2AsO4OH. It crystallizes in the monoclinic system , and is sometimes found in small brilliant crystals of simple prismatic habit terminated by domal faces...
, 30 AdamiteAdamiteAdamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with...
; 35 Paradamite, 40 Wilhelmkleinite, 60 Urusovite, 65 Theoparacelsite - 08.BC With only medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1: 05 Angelellite, 15 AerugiteAerugiteAerugite is a rare complex nickel arsenate mineral with a variably reported formula: Ni92AsO6. It forms green to deep blue-green trigonal crystals. It has a Mohs hardness of 4 and a specific gravity of 5.85 to 5.95....
- 08.BD With only medium-sized cations, (OH, etc.):RO4 = 2:1: 05 Cornwallite, 10 Arsenoclasite, 15 Parwelite, 30 CornubiteCornubiteCornubite is a rare secondary copper arsenate mineral with formula: Cu524. It was first described for its discovery in 1958 in Wheal Carpenter, Gwinear, Cornwall, England, UK. The name is from Cornubia, the medieval Latin name for Cornwall...
- 08.BE With only medium-sized cations, (OH, etc.):RO4 > 2:1: 20 ClinoclaseClinoclaseClinoclase is a hydrous copper arsenate mineral, Cu3AsO43. Clinoclase is a rare secondary copper mineral and forms acicular crystals in the fractured weathered zone above copper sulfide deposits. It occurs in vitreous, translucent dark blue to dark greenish blue colored crystals and botryoidal...
, 25 Gilmarite, 25 Arhbarite, 30 AllactiteAllactiteAllactite is a rare arsenate mineral of metamorphosed manganese zinc ore deposits. It is found in Sweden and New Jersey, USA. Its name originated from Greek αλλάκτειν meaning "to change", referring to the strong pleochroism of the mineral....
, 30 Flinkite, 35 Chlorophoenicite, 35 Magnesiochlorophoenicite, 40 Gerdtremmelite, 45 Arakiite, 45 Kraisslite, 45 Dixenite, 45 Hematolite, 45 Mcgovernite, 50 Synadelphite, 55 Holdenite, 60 Kolicite, 65 Sabelliite, 70 JarosewichiteJarosewichiteJarosewichite is a rare manganese arsenate mineral with formula: Mn2+3Mn3+6. It was first described in Franklin, New Jersey which is its only reported occurrence. Its chemical composition and structure are similar to chlorophoenicite. This mineral is orthorhombic with 2/m2/m2/m point group. Its...
, 75 Theisite - 08.BF With medium-sized and large cations, (OH, etc.):RO4 < 0.5:1: (none)
- 08.BG With medium-sized and large cations, (OH, etc.):RO4 = 0.5:1: 05 Arsenbrackebuschite, 05 Arsentsumebite, 05 Feinglosite
- 08.BH With medium-sized and large cations, (OH,etc.):RO4 = 1:1: 10 Durangite, 10 Maxwellite, 10 Tilasite; 30 Carminite, 30 SewarditeSewarditeSewardite is a rare arsenate mineral with formula of CaFe2+322. Sewardite was discovered in 1982 and named for the mineralogist, Terry M. Seward , a professor of geochemistry in Zürich, Switzerland.- Properties :...
; 35 AustiniteAustiniteAustinite is a member of the adelite-descloizite group, adelite subgroup, the Zn end member of the Cu-Zn series with conichalcite. It is the zinc analogue of cobaltaustinite and nickelaustinite. At one time “brickerite” was thought to be a different species, but it is now considered to be identical...
, 35 AdeliteAdeliteThe rare mineral adelite, is a calcium, magnesium, arsenate with chemical formula CaMgAsO4OH. It forms a solid solution series with the vanadium bearing mineral gottlobite...
, 35 DuftiteDuftiteDuftite is a relatively common arsenate mineral with the formula CuPb, related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the Adelite-Descloizite Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in...
-alpha, 35 Duftite-beta?, 35 ConichalciteConichalciteConichalcite, CaCu, is a relatively common arsenate mineral related to duftite . It is green, often botryoidal, and occurs in the oxidation zone of some metal deposits. It occurs with limonite, malachite, beudantite, adamite, cuproadamite, olivenite and smithsonite.- Formation :Conichalcite forms...
, 35 Gabrielsonite, 35 Nickelaustinite, 35 Cobaltaustinite, 35 Arsendescloizite; 45 BayldoniteBayldoniteBayldonite is a rare secondary mineral with the chemical formula PbCu322H2O. It was first discovered in Penberthy Croft Mine, Cornwall, England, UK. It is named after its discoverer, John Bayldon....
, 50 Paganoite - 08.BK With medium-sized and large cations, (OH, etc.): 10 Medenbachite, 10 Cobaltneustadtelite, 10 Neustadtelite, 25 Jamesite
- 08.BL With medium-sized and large cations, (OH, etc.):RO4 = 3:1: 05 BeudantiteBeudantiteBeudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe36SO4AsO4....
, 05 Hidalgoite, 05 Gallobeudantite, 05 Kemmlitzite, 05 Weilerite, 10 Arsenowaylandite*, 10 Segnitite, 10 Arsenogorceixite, 10 Arsenocrandallite, 10 Arsenogoyazite, 10 Dussertite, 10 Philipsbornite, 13 Arsenoflorencite-(Ce), 13 Arsenoflorencite-(La)*, 13 Arsenoflorencite-(Nd)*, 13 Graulichite-(Ce) - 08.BM With medium-sized and large cations, (OH, etc.):RO4 = 4:1: 05 Retzian-(Ce), 05 Retzian-(La), 05 Retzian-(Nd)
- 08.BN With only large cations, (OH, etc.):RO4 = 0.33:1: 05 Fermorite, 05 Johnbaumite, 05 Clinomimetite, 05 Hedyphane, 05 MimetiteMimetiteMimetite, whose name derives from the Greek Μιμητής mimethes, meaning "imitator", is an arsenate mineral which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name is a reference to mimetite's resemblance to the mineral pyromorphite...
, 05 Morelandite, 05 Svabite, 05 Turneaureite - 08.BO With only large cations, (OH, etc.):RO4 1:1: 10 Preisingerite, 15 Atelestite, 20 Sahlinite, 35 Kuznetsovite, 45 Schlegelite
- 08.C Arsenates without Additional Anions, with H2O
- 08.CA With small and large/medium cations: 35 WarikahniteWarikahniteWarikahnite is a rare zinc arsenate mineral of the triclinic crystal system with Hermann- Mauguin notation 1*, belonging to the space group P1*. It occurs in the second oxidation zone of the Tsumeb mine in Namibia on corroded tennantite in the second oxidation zone under hydrothermal conditions in...
, 50 KeyiteKeyiteKeyite is a mineral with the chemical formula 6 · 2O. The name comes from Charles Locke Key , an American mineral dealer who furnished its first specimens....
, 55 Pushcharovskite, 60 Prosperite - 08.CB With only medium-sized cations, RO4:H2O = 1:1: 10 IMA2008-066, 10 IMA2008-047, 10 Sainfeldite, 10 Villyaellenite; 15 Krautite, 15 FluckiteFluckiteFluckite is a mineral with the chemical formula CaMnH22·2H2O Fluckite is named after the mineralogist Pierre Fluck of Louis Pasteur University in Strasbourg, France. Fluckite's mineral crystallography is triclinic meaning it has three axis of different length and three different interior angles...
; 20 Cobaltkoritnigite, 20 Koritnigite; 25 Yvonite, 30 Geminite, 40 Radovanite, 55 Irhtemite, 60 Burgessite - 08.CC With only medium-sized cations, RO4:H2O = 1:1.5: 10 KaatialaiteKaatialaiteKaatialaite is a ferric arsenate mineral found in Finland.- External links :* from mindat.org* from...
, 15 Leogangite - 08.CD With only medium-sized cations, RO4:H2O = 1:2: 10 Mansfieldite, 10 ScoroditeScoroditeScorodite is a common hydrated iron arsenate mineral, with the chemical formula FeAsO4·2H2O. It is found in hydrothermal deposits and as a secondary mineral in gossans worldwide. Scorodite weathers to limonite....
, 10 Yanomamite; 15 Parascorodite, 25 Sterlinghillite, 30 Rollandite - 08.CE With only medium-sized cations, RO4:H2O £ 1:2.5: 05 GeigeriteGeigeriteGeigerite is a mineral, a complex hydrous manganese arsenate with formula: Mn522·10H2O. It forms triclinic pinacoidal vitreous colorless, red to brown crystals. It has a Mohs hardness of 3 and a specific gravity of 3.05....
, 05 Chudobaite, 15 BrassiteBrassiteBrassite is a mineral with the chemical formula Mg·4. It is found in the Czech Republic. It is white and leaves a white streak. It has perfect cleavage. Its crystals are orthorhombic - dipyramidal....
, 20 Rosslerite, 30 Veselovskyite, 30 IMA2008-010, 30 Lindackerite, 40 Ferrisymplesite, 40 Manganohornesite, 40 AnnabergiteAnnabergiteAnnabergite is an arsenate mineral consisting of a hydrous nickelarsenate, Ni32·8H2O, crystallizing in the monoclinic system and isomorphous with vivianite and erythrite. Crystals are minute and capillary and rarely met with, the mineral occurring usually as soft earthy masses and encrustations. A...
, 40 Erythrite, 40 Hornesite, 40 Kottigite, 40 Parasymplesite, 45 Symplesite, 60 KankiteKankiteKankite is a mineral with the chemical formula Fe3+AsO4·3.5. Kankite is named for the locality that yielded first specimens Kank, Czech Republic. Kankite forms in old mine dumps...
, 85 Metakottigite - 08.CF With large and medium-sized cations, RO4:H2O > 1:1: 05 Grischunite
- 08.CG With large and medium-sized cations, RO4:H2O = 1:1: 05 Gaitite, 05 Parabrandtite, 05 Talmessite, 10 RoseliteRoseliteRoselite is a rare arsenate mineral with chemical formula: Ca2[AsO4]2·H2O.It was first described in 1825 for an occurrence in the Rappold mines of Schneeberg, Saxony, Germany and named for German mineralogist Gustav Rose who discovered this mineral...
, 10 Roselite-beta, 10 Brandtite, 10 Zincroselite, 10 Wendwilsonite, 15 Ferrilotharmeyerite, 15 CabalzariteCabalzariteCabalzarite Cabalzarite Cabalzarite (Ca(Mg,Al,Fe3+)2[AsO4]2·20(H2O,OH) is a mineral first found in an abandoned mine in Falotta, Graubünden, Switzerland and named for Walter Cabalzar, an amateur mineralogist of Chur, Switzerland who contributed to the mineralogy of the Graubünden canton....
, 15 Lotharmeyerite, 15 Cobaltlotharmeyerite, 15 Mawbyite, 15 Cobalttsumcorite, 15 Nickellotharmeyerite, 15 Schneebergite, 15 Nickelschneebergite, 15 TsumcoriteTsumcoriteTsumcorite is a rare hydrated lead arsenate mineral that was discovered in 1971, and reported by Geier, Kautz and Muller. It was named after the TSUMeb CORporation mine at Tsumeb, in Namibia, in recognition of the Corporation’s support for mineralogical investigations of the orebody at its Mineral...
, 15 Thometzekite, 15 Manganlotharmeyerite; 20 Zincgartrellite, 20 Lukrahnite, 20 Gartrellite, 20 Helmutwinklerite, 20 Rappoldite; 35 Nickeltalmessite - 08.CH With large and medium-sized cations, RO4:H2O < 1:1: 05 Walentaite, 15 PicropharmacolitePicropharmacolitePicropharmacolite, Ca4Mg22·11H2O, is a rare arsenate mineral. It was named in 1819 from the Greek for bitter, in allusion to its magnesium content, and its chemical similarity to pharmacolite. The mineral irhtemite, Ca4Mg22·4H2O, has the same composition as picropharmacolite, except that it has...
; 55 Smolianinovite, 55 Fahleite; 60 Barahonaite-(Fe), 60 Barahonaite-(Al) - 08.CJ With only large cations: 20 HaidingeriteHaidingeriteHaidingerite is a calcium arsenate mineral with formula Ca·H2O. It crystallizes in the orthorhombic crystal system as short prismatic to equant...
, 25 VladimiriteVladimiriteVladimirite has a general chemical formula of Ca5 [2|2]·5H2O. It is named after the Vladimirovskoye deposit in Russia, where it was discovered in the 1950s...
, 30 Ferrarisite, 35 Machatschkiite; 40 Phaunouxite, 40 Rauenthalite; 50 Pharmacolite, 55 Mcnearite, 75 Guerinite
- 08.CA With small and large/medium cations: 35 Warikahnite
- 08.D Arsenates
- 08.DA With small (and occasionally larger) cations: 05 Bearsite, 35 Philipsburgite
- 08.DB With only medium-sized cations, (OH, etc.):RO4 < 1:1: 05 Pitticite, 35 Sarmientite, 40 BukovskyiteBukovskyiteBukovskyite is an iron arsenate sulfate mineral with formula: Fe2·7H2O which forms nodules with a reniform surface. Under a microscope, these nodules appear as a collection of minute needles similar to gypsum...
, 45 ZykaiteZykaiteZykaite or zýkaite is a grey-white mineral consisting of arsenic, hydrogen, iron, sulfur and oxygen with formula: Fe3+43·15. This dull mineral is very soft with a Mohs hardness of only 2 and a specific gravity of 2.5...
, 75 Braithwaiteite - 08.DC With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1: 07 EuchroiteEuchroiteEuchroite is a hydrated copper arsenate hydroxide mineral with formula: Cu2AsO4OH·3H2O. It is a vitreous green to emerald green mineral crystallizing in the orthorhombic system. It has a Mohs hardness of 3.5 - 4.0 and a specific gravity of 3.39 - 3.45. It was first described in 1823 in Ľubietová,...
, 10 LegranditeLegranditeLegrandite is a rare zinc arsenate mineral, Zn2·.It is an uncommon secondary mineral in the oxidized zone of zincn–arsenic bearing deposits and occurs rarely in granite pegmatite. Associated minerals include: adamite, paradamite, kottigite, scorodite, smithsonite, leiteite, renierite,...
, 12 Strashimirite; 15 Bendadaite, 15 Cobaltarthurite, 15 ArthuriteArthuriteArthurite is a mixture of divalent copper and iron ions in combination with trivalent arsenate, phosphate and sulfate ions with hydrogen and oxygen...
, 15 Ojuelaite; 30 Maghrebite, 55 Mapimite, 57 Ogdensburgite - 08.DD With only medium-sized cations, (OH, etc.):RO4 = 2:1: 05 Chenevixite, 05 Luetheite; 10 AkrochorditeAkrochorditeAkrochordite is an exceptionally rare hydrated hydrous arsenate mineral of the formula 424.4H2O and represents a small group of rare in the nature manganese arsenates and, similarly to most other Mn-bearing arsenates, possess pinkish colour. It is typically associated with metamorphic Mn deposits....
, 10 Guanacoite - 08.DE With only medium-sized cations, (OH, etc.):RO4 = 3:1: 15 Bulachite, 25 Ceruleite, 40 Juanitaite
- 08.DF With only medium-sized cations, (OH,etc.):RO4 > 3:1: 10 Liskeardite, 20 LiroconiteLiroconiteLiroconite is a complex mineral: Hydrated copper aluminium arsenate hydroxide, with the formula Cu2Al[4|AsO4]·4. It is a vitreous monoclinic mineral, colored bright blue to green, often associated with malachite, azurite, olivenite, and clinoclase...
, 30 ChalcophylliteChalcophylliteChalcophyllite is a rare secondary copper arsenate mineral occurring in the oxidized zones of some arsenic-bearing copper deposits. It was first described from material collected in Germany...
, 35 Parnauite - 08.DG With large and medium-sized cations, (OH, etc.):RO4 < 0.5:1: 05 Shubnikovite, 05 LavendulanLavendulanLavendulan is an uncommon copper arsenate mineral, known for its characteristic intense electric blue color. It belongs to the lavendulan group, which has four members:* Lavendulan NaCaCu54Cl.5H2O* Lemanskiite NaCaCu54Cl.5H2O...
, 05 Zinclavendulan?, 05 Lemanskiite, 05 Zdenekite - 08.DH With large and medium-sized cations, (OH, etc.):RO4 < 1:1: 30 ArseniosideriteArseniosideriteArseniosiderite is a rare arsenate mineral formed by the oxidation of other arsenic-containing minerals, such as scorodite or arsenopyrite. It occurs in association with beudantite, carminite, dussertite, pharmacolite, pitticite, adamite and erythrite. The name arseniosiderite reflects two major...
, 30 Kolfanite, 30 Sailaufite; 45 Mahnertite; 50 AndyrobertsiteAndyrobertsiteAndyrobertsite is a rare, complex arsenate mineral with a blue color. It is found in the Tsumeb mine in Namibia and named after Andrew C. Roberts , mineralogist with the Geological Survey of Canada. A Ca-rich analogue is called calcioandyrobertsite and has a more greenish tint....
, 50 Calcioandyrobertsite-1M, 50 Calcioandyrobertsite-2O; 60 Bouazzerite - 08.DJ With large and medium-sized cations, (OH, etc.):RO4 = 1:l: 15 Camgasite, 45 Attikaite
- 08.DK With large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1: 10 Alumopharmacosiderite, 10 Barium-alumopharmacosiderite?, 10 Bariopharmacosiderite, 10 PharmacosideritePharmacosideritePharmacosiderite is a hydrated basic ferric arsenate, with chemical formula KFe434·H2O and a molecular weight of 873.38 g/mol. It consists of the elements arsenic, iron, hydrogen, potassium, sodium and oxygen. It has a Mohs hardness of 2 to 3, about that of a finger nail...
, 10 Natropharmacosiderite, 10 Barium-zinc-alumopharmacosiderite*; 25 Richelsdorfite - 08.DL With large and medium-sized cations, (OH, etc.):RO4 = 2:1: 15 AgarditeAgarditeAgardite is a mineral group consisting of agardite-, agardite-, agardite-, and agardite-. They comprise a group of minerals that are hydrous hydrated arsenates of rare earth elements and copper, which contain variable amounts of calcium and sometimes lead...
-(Dy), 15 Agardite-(Ca), 15 Agardite-(Ce), 15 Agardite-(La), 15 Agardite-(Nd), 15 Agardite-(Y), 15 Goudeyite, 15 Zalesiite, 15 MixiteMixiteMixite is a rare copper bismuth arsenate mineral with formula: BiCu636·3. It crystallizes in the hexagonal crystal system typically occurring as radiating acicular prisms and massive encrustations. The color varies from white to various shades of green and blue. It has a Mohs hardness of 3.5 to 4...
, 15 Plumboagardite, 20 Joelbruggerite, 20 Wallkilldellite-(Fe), 20 Wallkilldellite - 08.DM With large and medium-sized cations, (OH, etc.):RO4 > 2:1: 05 Esperanzaite, 10 Clinotyrolite, 10 TyroliteTyroliteTyrolite is a hydrated calcium copper arsenate carbonate mineral with formula: CaCu52CO34·6H2O. Tyrolite forms glassy blue to green orthorhombic radial crystals and botryoidal masses. It has a Mohs hardness of 1.5 to 2 and a specific gravity of 3.1 to 3.2...
, 15 Natrobetpakdalite, 15 Betpakdalite, 25 Yukonite
- 08.E Uranyl Arsenates
- 08.EA UO2:RO4 = 1:2: 05 Orthowalpurgite, 05 Walpurgite; 10 Hallimondite
- 08.EB UO2:RO4 = 1:1: 05 Metarauchite, 05 Heinrichite, 05 Kahlerite, 05 Novacekite, 05 Uranospinite, 05 ZeuneriteZeuneriteZeunerite is a green copper uranium arsenate mineral with formula Cu22•10-16. It is a member of the autunite group. Metazeunerite is a dehydration product....
; 10 MetazeuneriteMetazeuneriteMetazeunerite is an arsenate mineral with a chemical formula of Cu22·8H2O. The origin of this mineral comes from the dehydration process that metazeunerite must go through, and it’s association with zeunerite. As dehydration occurs, zeunerite loses an electron and is then metamorphosed into...
, 10 Metauranospinite, 10 Metaheinrichite, 10 Metakahlerite, 10 Metakirchheimerite, 10 Metalodevite, 10 Metanovacekite; 15 Uramarsite, 15 Trogerite, 15 AbernathyiteAbernathyiteAbernathyite is a rare hydrous uranium oxide mineral with chemical formula K222·6H2O. It occurs as a secondary fracture filling mineral. It crystallizes in the tetragonal system and forms yellow vitreous tabular crystals with perfect cleavage...
, 15 Natrouranospinite; 20 Chistyakovaite, 25 Arsenuranospathite - 08.EC UO2:RO4 = 3:2: 10 Arsenuranylite, 15 Hugelite, 20 Arsenovanmeersscheite, 45 Nielsbohrite
- 08.ED Unclassified: 10 Asselbornite
- 08.F Polyarsenates
- 08.FA Polyarsenates, without OH and H2O; dimers of corner-sharing RO4 tetrahedra: 25 Petewilliamsite
- 08.X Unclassified Strunz Arsenates
- 08.XX Unknown: 00 Kamarizaite, 00 Chernovite-(Ce)*, 00 Arsenobismite?, 00 Slavkovite, 00 Lapeyreite, 00 IMA2000-020, 00 IMA2008-063, 00 IMA2009-002, IMA2009-016
Class: vanadates
- 04.H V[5,6] Vanadates
- 04.HB Uranyl Sorovanadates: 05 CarnotiteCarnotiteCarnotite is a potassium uranium vanadate radioactive mineral with chemical formula: K222·3H2O. The water content can vary and small amounts of calcium, barium, magnesium, iron, and sodium are often present.-Occurrence:...
, 05 MargaritasiteMargaritasiteMargaritasite is a yellow, caesium-bearing mineral in the carnotite group. Its chemical formula is 22V2O8·H2O and its crystal system is monoclinic.-Name and discovery:...
; 10 Sengierite; 15 Fritzscheite, 15 Curienite, 15 FrancevilliteFrancevilliteFrancevillite is a uranyl-group vanadate mineral in the tyuyamunite series. Its chemical formula is 2V2O8·5. Francevillite is a strongly radioactive mineral. It is typically orange, yellow or brownish yellow. It forms a series with curienite....
; 20 Metavanuralite, 20 Vanuralite; 25 Metatyuyamunite, 25 Tyuyamunite; 30 Strelkinite, 35 Uvanite, 40 Rauvite - 04.HC [6]-Sorovanadates: 05 Magnesiopascoite, 05 Lasalite, 05 Pascoite; 10 Hummerite, 15 Sherwoodite
- 04.HD Inovanadates: 05 Rossite, 10 Metarossite, 15 Munirite, 20 Metamunirite, 25 Dickthomssenite, 30 Ansermetite
- 04.HE Phyllovanadates: 05 Melanovanadite, 10 Shcherbinaite; 15 Hewettite, 15 Metahewettite; 20 Bokite, 20 Bariandite, 20 Corvusite, 20 Fernandinite, 20 Straczekite; 25 Haggite, 30 Doloresite, 35 Duttonite, 40 Cavoite
- 04.HF Tektovanadates: 05 Bannermanite
- 04.HG Unclassified V oxides: 05 Fervanite, 10 Huemulite, 15 Vanalite, 20 Simplotite, 25 Vanoxite, 30 Navajoite, 35 Delrioite, 40 Metadelrioite, 45 Barnesite, 50 Hendersonite, 55 Grantsite, 60 Lenoblite, 65 Satpaevite
- 04.HB Uranyl Sorovanadates: 05 Carnotite
- 08.A Vanadates without additional anions, without H2O
- 08.AB With medium-sized cations: 35 Mcbirneyite, 40 LyonsiteLyonsiteLyonsite is a rare black vanadate mineral that is opaque with a metallic lustre. It crystallizes in the orthorhombic crystal system. Lyonsite often occurs as small tabular typically well formed crystals. Lyonsite has a good cleavage and a dark gray streak.Lyonsite occurs as a sublimate in volcanic...
- 08.AC With medium-sized and large cations: 05 Howardevansite; 25 Palenzonaite, 25 SchaferiteSchäferiteSchäferite is a rare vanadate mineral with chemical formula Ca2NaMg2[VO4]3. Schäferite is isometric, which means that it has three axes of equal length and 90° angles between the axes. Schäferite belongs to the optical class Isotropic, meaning that the velocity of light is the same no matter which...
; 75 Ronneburgite, 80 Tillmannsite - 08.AD With only large cations: 35 WakefielditeWakefielditeWakefieldite is an uncommon rare earth element vanadate mineral. There are four main types of wakefieldite- wakefieldite-, wakefieldite-, wakefieldite-, and wakefieldite-, depending upon the dominant rare earth metal ion present. Wakefieldite has a Mohs hardness ranging from 4-5. Wakefieldite...
-(La), 35 Wakefieldite-(Nd), 35 Wakefieldite-(Ce), 35 Wakefieldite-(Y), 35 Dreyerite; 40 Pucherite, 65 Clinobisvanite
- 08.AB With medium-sized cations: 35 Mcbirneyite, 40 Lyonsite
- 08.B Vanadates with Additional Anions, without H2O
- 08.BB With only medium-sized cations, (OH, etc.):RO4 £ 1:1: 50 Namibite, 70 Turanite, 75 Stoiberite, 80 Fingerite, 85 Averievite
- 08.BD With only medium-sized cations, (OH, etc.):RO4 = 2:1: 20 Reppiaite
- 08.BE With only medium-sized cations, (OH, etc.):RO4 > 2:1: 45 Turtmannite, 80 Coparsite
- 08.BF With medium-sized and large cations, (OH, etc.):RO4 < 0.5:1: 20 Nabiasite
- 08.BG With medium-sized and large cations, (OH, etc.):RO4 = 0.5:1: 05 Brackebuschite, 05 Gamagarite, 05 TokyoiteTokyoiteTokyoite is a rare barium manganese vanadate mineral with the chemical formula: Ba2OH2. It is the manganese analogue of the iron rich gamagarite and the barium analogue of the lead vanadate, brackebuschite....
, 05 Bushmakinite, 05 Calderonite - 08.BH With medium-sized and large cations, (OH,etc.):RO4 = 1:1: 35 Tangeite, 35 Gottlobite, 40 Descloizite, 40 Cechite, 40 Pyrobelonite, 40 MottramiteMottramiteMottramite is an orthorhombic mineral, PbCu, at the copper end of the descloizite group. It was formerly called cuprodescloizite or psittacinite .-References:***...
, 40 Duhamelite?, 45 Vesignieite, 65 Leningradite - 08.BK With medium-sized and large cations, (OH, etc.): 20 Heyite
- 08.BL With medium-sized and large cations, (OH, etc.):RO4 = 3:1: 20 Dugganite, 20 Cheremnykhite
- 08.BN With only large cations, (OH, etc.):RO4 = 0.33:1: 05 VanadiniteVanadiniteVanadinite is a mineral belonging to the apatite group of phosphates, with the chemical formula Pb53Cl. It is one of the main industrial ores of the metal vanadium and a minor source of lead. A dense, brittle mineral, it is usually found in the form of red hexagonal crystals. It is an uncommon...
- 08.BO With only large cations, (OH, etc.):RO4 1:1: 10 Schumacherite, 15 Hechtsbergite, 20 Kombatite
- 08.C Vanadates without Additional Anions, with H2O
- 08.CB With only medium-sized cations, RO4:H2O = 1:1: 35 Schubnelite, 45 Kazakhstanite, 50 Kolovratite
- 08.CE With only medium-sized cations, RO4:H2O £ 1:2.5: 65 Steigerite; 70 Metaschoderite, 70 Schoderite
- 08.CG With large and medium-sized cations, RO4:H2O = 1:1: 15 Mounanaite, 15 Krettnichite, 25 Pottsite
- 08.CJ With only large cations: 65 SincositeSincositeSincosite is a green mineral discovered in 1922. It is named for Sincos, Daniel Alcides Carrión Province, Peru, where it was first discovered....
, 65 Bariosincosite
- 08.D Vanadates
- 08.DC With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1: 32 Tinticite; 60 Cloncurryite
- 08.DF With only medium-sized cations, (OH,etc.):RO4 > 3:1: 15 Rusakovite
- 08.DM With large and medium-sized cations, (OH, etc.):RO4 > 2:1: 20 Phosphovanadylite, 40 Santafeite
- 08.F [4]-Polyvanadates
- 08.FA [4]-Polyvanadates, without OH and H2O; dimers of corner-sharing RO4 tetrahedra: 05 Blossite, 10 ZiesiteZiesiteZiesite is a mineral, copper vanadate: formula β-Cu2V2O7. It was discovered in 1980 as monoclinic crystals around fumaroles in the crater of the Izalco Volcano, El Salvador. It is named after Emmanuel G. Zies , an American mineralogist....
, 15 Chervetite - 08.FC [4]-Polyvanadates, with H2O only: 05 Fianelite, 15 Pintadoite
- 08.FD [4]-Polyvanadates, with OH and H2O: 05 Martyite, 05 VolborthiteVolborthiteVolborthite is a mineral containing copper and vanadium, with the formula Cu3V2O72·2H2O. Found originally in 1838 in the Urals, it was named for Alexander von Volborth , a Russian paleontologist....
- 08.FE Ino-[4]-vanadates: 05 Ankinovichite, 05 Alvanite
- 08.FA [4]-Polyvanadates, without OH and H2O; dimers of corner-sharing RO4 tetrahedra: 05 Blossite, 10 Ziesite
- 08.X Unclassified Strunz Vanadates
- 08.XX Unknown: 00 Vanuranylite?